Joan Valentine, Ph.D.

A Short Biography:

Joan Selverstone Valentine graduated from Smith College in Northampton, Massachusetts in 1967 with an A.B. in Chemistry. Four years later, she was the first woman to receive a Ph.D. in Chemistry from Princeton University. After a year as an Instructor at Princeton, she was appointed Assistant Professor of Chemistry at Rutgers University in New Brunswick, New Jersey in 1972. In 1980, she joined the faculty of UCLA in the Department of Chemistry and Biochemistry.


Work Titles
UCLA Professor, Chemistry and Biochemistry Professor, Biochemistry, Molecular Biology Member, Basic/Translational Research, Jonsson Comprehensive Cancer Center Member, Graduate Program in Biochemistry, Molecular and Structural Biology Member, Molecular Biology Institute Researcher, Biochemistry Researcher, Chemical Biology Researcher, Inorganic
Education:
Degrees:
Ph.D., Princeton University
A.B., Smith College
Fellowship:
AAAS, Fellow
Honors and Awards:
John C. Bailar, Jr. Medal
Smith Medal
NIH, Research Career Development Award
McCoy Award
UCLA, Alpha Chi Sigma Faculty Research
Professional Societies:
Accounts of Chemical Research, Editor-in-Chief
2007 Cal. Tech., Ernest K. Swift Lecturer
2007 U. of Maryland, Rollinson Lecturer
2005 National Academy of Sciences, Member

Contact Information:

Work Email Address:

jsv@chem.ucla.edu


Fax Number:

(310) 206-9880

Lab Number:

310-825-2807

Work Phone Number:

310-825-1790

310-825-9835

Laboratory Address:

Young Hall 4064 & 4033
Mail Code: 156905


Work Address:

Young Hall 4037
Mail Code: 156905

Journal Accts. Chem. Res.
Young Hall 4048


Detailed Biography:

Joan Selverstone Valentine was born in Auburn, California in 1945. She grew up in Cambridge, Massachusetts and received her primary education there at Shady Hill School. Her high school years were spent at Chatham Hall School in Chatham, Virginia. She graduated with degrees in Chemistry from Smith College (B. A.) and Princeton University (Ph.D.), after which she taught for a year at Princeton. In 1972 she moved to Rutgers University, serving as Assistant, and then Associate, Professor of Chemistry. In 1980 she came to UCLA and joined the faculty of the Department of Chemistry and Biochemistry, where she was made Professor in 1981. She served as Departmental Vice Chair for Research and Administration from 1991 to 1994, and was Director of the UCLA Chemistry-Biology Interface Predoctoral Training Program from 1993 to 2001. In addition to her research and teaching activities at UCLA, Professor Valentine served as Associate Editor of the journal Inorganic Chemistry from 1989 to 1995 and as Editor-in-Chief of the American Chemical Society journal Accounts of Chemical Research from 1994 to the present. She has also served on a number of Boards and Advisory committees, including National Library of Medicine Literature Selection Technical Review Committee (2000-2004), the Carnegie Foundation Initiative on the Doctorate Chemistry Advisory Committee (2002-present), the Board of Trustees of the Gordon Research Conferences (2002-2007), the Visiting Committee for the Division of Chemistry and Chemical Engineering, California Institute of Technology (2002-present) and the Board of Directors of the Research Corporation (1986-2004).

Publications:

A selected list of publications:

Leal Sónia S, Cardoso Isabel, Valentine Joan S, Gomes Cláudio M   Calcium ions promote superoxide dismutase 1 (SOD1) aggregation into non fibrillar amyloid: a link to toxic effects of calcium overload in amyotrophic lateral sclerosis (ALS)? The Journal of biological chemistry, 2013; .
Chan Pik K, Chattopadhyay Madhuri, Sharma Shivani, Souda Puneet, Gralla Edith Butler, Borchelt David R, Whitelegge Julian P, Valentine Joan Selverstone   Structural similarity of wild-type and ALS-mutant superoxide dismutase-1 fibrils using limited proteolysis and atomic force microscopy Proceedings of the National Academy of Sciences of the United States of America, 2013; 110(27): 10934-9.
Sheng Yuewei, Durazo Armando, Schumacher Mikhail, Gralla Edith Butler, Cascio Duilio, Cabelli Diane E, Valentine Joan Selverstone   Tetramerization reinforces the dimer interface of MnSOD PloS one, 2013; 8(5): e62446.
Sheng Yuewei, Butler Gralla Edith, Schumacher Mikhail, Cascio Duilio, Cabelli Diane E, Valentine Joan Selverstone   Six-coordinate manganese(3+) in catalysis by yeast manganese superoxide dismutase Proceedings of the National Academy of Sciences of the United States of America, 2012; 109(36): 14314-9.
Prudencio Mercedes, Lelie Herman, Brown Hilda H, Whitelegge Julian P, Valentine Joan S, Borchelt David R   A novel variant of human superoxide dismutase 1 harboring amyotrophic lateral sclerosis-associated and experimental mutations in metal-binding residues and free cysteines lacks toxicity in vivo Journal of neurochemistry, 2012; 121(3): 475-85.
Barnese Kevin, Gralla Edith Butler, Valentine Joan Selverstone, Cabelli Diane E   Biologically relevant mechanism for catalytic superoxide removal by simple manganese compounds Proceedings of the National Academy of Sciences of the United States of America, 2012; 109(18): 6892-7.
Latifi Reza, Valentine Joan S, Nam Wonwoo, de Visser Sam P   Predictive studies of H-atom abstraction reactions by an iron(IV)-oxo corrole cation radical oxidant Chemical communications (Cambridge, England), 2012; 48(29): 3491-3.
Sheng Yuewei, Chattopadhyay Madhuri, Whitelegge Julian, Valentine Joan Selverstone   SOD1 aggregation and ALS: role of metallation states and disulfide status Current topics in medicinal chemistry, 2012; 12(22): 2560-72.
Sheng Yuewei, Stich Troy A, Barnese Kevin, Gralla Edith B, Cascio Duilio, Britt R David, Cabelli Diane E, Valentine Joan Selverstone   Comparison of two yeast MnSODs: mitochondrial Saccharomyces cerevisiae versus cytosolic Candida albicans Journal of the American Chemical Society, 2011; 133(51): 20878-89.
Li Yanran, Chooi Yit-Heng, Sheng Yuewei, Valentine Joan S, Tang Yi   Comparative characterization of fungal anthracenone and naphthacenedione biosynthetic pathways reveals an α-hydroxylation-dependent Claisen-like cyclization catalyzed by a dimanganese thioesterase Journal of the American Chemical Society, 2011; 133(39): 15773-85.
Cho Jaeheung, Jeon Sujin, Wilson Samuel A, Liu Lei V, Kang Eun A, Braymer Joseph J, Lim Mi Hee, Hedman Britt, Hodgson Keith O, Valentine Joan Selverstone, Solomon Edward I, Nam Wonwoo   Structure and reactivity of a mononuclear non-haem iron(III)-peroxo complex Nature, 2011; 478(7370): 502-5.
Sehati Sadaf, Clement Matthew H S, Martins Jake, Xu Lei, Longo Valter D, Valentine Joan S, Gralla Edith B   Metabolic alterations in yeast lacking copper-zinc superoxide dismutase Free radical biology & medicine, 2011; .
Lelie Herman L, Liba Amir, Bourassa Megan W, Chattopadhyay Madhuri, Chan Pik K, Gralla Edith B, Miller Lisa M, Borchelt David R, Valentine Joan Selverstone, Whitelegge Julian P   Copper and zinc metallation status of copper-zinc superoxide dismutase from amyotrophic lateral sclerosis transgenic mice The Journal of biological chemistry, 2011; 286(4): 2795-806.
Kim Sun Hee, Park Hyejin, Seo Mi Sook, Kubo Minoru, Ogura Takashi, Klajn Jan, Gryko Daniel T, Valentine Joan Selverstone, Nam Wonwoo   Reversible O-O bond cleavage and formation between Mn(IV)-peroxo and Mn(V)-oxo corroles Journal of the American Chemical Society, 2010; 132(40): 14030-2.
Barnese Kevin, Sheng Yuewei, Stich Troy A, Gralla Edith B, Britt R David, Cabelli Diane E, Valentine Joan Selverstone   Investigation of the Highly Active Manganese Superoxide Dismutase from Saccharomyces cerevisiae Journal of the American Chemical Society, 2010; .
McNaughton Rebecca L, Reddi Amit R, Clement Matthew H S, Sharma Ajay, Barnese Kevin, Rosenfeld Leah, Gralla Edith Butler, Valentine Joan Selverstone, Culotta Valeria C, Hoffman Brian M   Probing in vivo Mn2+ speciation and oxidative stress resistance in yeast cells with electron-nuclear double resonance spectroscopy Proceedings of the National Academy of Sciences of the United States of America, 2010; 107(35): 15335-9.
Seetharaman Sai V, Winkler Duane D, Taylor Alexander B, Cao Xiaohang, Whitson Lisa J, Doucette Peter A, Valentine Joan S, Schirf Virgil, Demeler Borries, Carroll Mark C, Culotta Valeria C, Hart P John   Disrupted zinc-binding sites in structures of pathogenic SOD1 variants D124V and H80R Biochemistry, 2010; 49(27): 5714-25.
de Visser Sam P, Valentine Joan Selverstone, Nam Wonwoo   A biomimetic ferric hydroperoxo porphyrin intermediate Angewandte Chemie (International ed. in English), 2010; 49(12): 2099-101.
Durazo Armando, Shaw Bryan F, Chattopadhyay Madhuri, Faull Kym F, Nersissian Aram M, Valentine Joan Selverstone, Whitelegge Julian P   Metal-free superoxide dismutase-1 and three different amyotrophic lateral sclerosis variants share a similar partially unfolded beta-barrel at physiological temperature The Journal of biological chemistry, 2009; 284(49): 34382-9.
Tiwari Ashutosh, Liba Amir, Sohn Se Hui, Seetharaman Sai V, Bilsel Osman, Matthews C Robert, Hart P John, Valentine Joan Selverstone, Hayward Lawrence J   Metal deficiency increases aberrant hydrophobicity of mutant superoxide dismutases that cause amyotrophic lateral sclerosis The Journal of biological chemistry, 2009; 284(40): 27746-58.
Oztug Durer Zeynep A, Cohlberg Jeffrey A, Dinh Phong, Padua Shelby, Ehrenclou Krista, Downes Sean, Tan James K, Nakano Yoko, Bowman Christopher J, Hoskins Jessica L, Kwon Chuhee, Mason Andrew Z, Rodriguez Jorge A, Doucette Peter A, Shaw Bryan F, Valentine Joan Selverstone   Loss of metal ions, disulfide reduction and mutations related to familial ALS promote formation of amyloid-like aggregates from superoxide dismutase PloS one, 2009; 4(3): e5004.
Pollard Julianne M, Reboucas Julio S, Durazo Armando, Kos Ivan, Fike Francesca, Panni Moeen, Gralla Edith Butler, Valentine Joan Selverstone, Batinic-Haberle Ines, Gatti Richard A   Radioprotective effects of manganese-containing superoxide dismutase mimics on ataxia-telangiectasia cells Free radical biology & medicine, 2009; 47(3): 250-60.
Chattopadhyay Madhuri, Valentine Joan Selverstone   Aggregation of Copper-Zinc Superoxide Dismutase in Familial and Sporadic ALS Antioxidants & Redox Signaling, 2009; 11(7): 1603-14.
Chattopadhyay Madhuri, Durazo Armando, Sohn Se Hui, Strong Cynthia D, Gralla Edith B, Whitelegge Julian P, Valentine Joan Selverstone   Initiation and elongation in fibrillation of ALS-linked superoxide dismutase Proceedings of the National Academy of Sciences of the United States of America, 2008; 105(48): 18663-8.
Valentine Joan Selverstone, Gralla Edith Butler   Reactive oxygen species special feature Proceedings of the National Academy of Sciences of the United States of America, 2008; 105(24): 8178.
Barnese Kevin, Gralla Edith B, Cabelli Diane E, Valentine Joan Selverstone   Manganous phosphate acts as a superoxide dismutase Journal of the American Chemical Society, 2008; 130(14): 4604-6.
Shaw Bryan F, Lelie Herman L, Durazo Armando, Nersissian Aram M, Xu Guillan, Chan Pik K, Gralla Edith B, Tiwari Ashutosh, Hayward Lawrence J, Borchelt David R, Valentine Joan S, Whitelegge Julian P   Detergent-insoluble aggregates associated with amyotrophic lateral sclerosis in transgenic mice contain primarily full-length, unmodified superoxide dismutase-1 The Journal of Biological Chemistry, 2008; 283(13): 8340-50.
Munroe William, Kingsley Carolyn, Durazo Armando, Gralla Edith Butler, Imlay James A, Srinivasan Chandra, Valentine Joan Selverstone   Only one of a wide assortment of manganese-containing SOD mimicking compounds rescues the slow aerobic growth phenotypes of both Escherichia coli and Saccharomyces cerevisiae strains lacking superoxide dismutase enzymes Journal of inorganic biochemistry, 2007; 101(11-12): 1875-82.
Banci Lucia, Bertini Ivano, D'Amelio Nicola, Libralesso Elisa, Turano Paola, Valentine Joan Selverstone   Metalation of the amyotrophic lateral sclerosis mutant glycine 37 to arginine superoxide dismutase (SOD1) apoprotein restores its structural and dynamical properties in solution to those of metalated wild-type SOD1 Biochemistry, 2007; 46(35): 9953-62.
Banci Lucia, Bertini Ivano, Durazo Armando, Girotto Stefania, Gralla Edith Butler, Martinelli Manuele, Valentine Joan Selverstone, Vieru Miguela, Whitelegge Julian P   Metal-free superoxide dismutase forms soluble oligomers under physiological conditions: a possible general mechanism for familial ALS Proceedings of the National Academy of Sciences of the United States of America, 2007; 104(27): 11263-7.
Potter Soshanna Zittin, Zhu Haining, Shaw Bryan Francis, Rodriguez Jorge A, Doucette Peter A, Sohn Se Hui, Durazo Armando, Faull Kym F, Gralla Edith Butler, Nersissian Aram M, Valentine Joan Selverstone   Binding of a single zinc ion to one subunit of copper-zinc superoxide dismutase apoprotein substantially influences the structure and stability of the entire homodimeric protein Journal of the American Chemical Society, 2007; 129(15): 4575-83.
Shaw Bryan F, Valentine Joan Selverstone   How do ALS-associated mutations in superoxide dismutase 1 promote aggregation of the protein? Trends in biochemical sciences, 2007; 32(2): 78-85.
Ferri Alberto, Cozzolino Mauro, Crosio Claudia, Nencini Monica, Casciati Arianna, Gralla Edith Butler, Rotilio Giuseppe, Valentine Joan Selverstone, Carrì Maria Teresa   Familial ALS-superoxide dismutases associate with mitochondria and shift their redox potentials Proceedings of the National Academy of Sciences of the United States of America, 2006; 103(37): 13860-5.
Shaw Bryan Francis, Durazo Armando, Nersissian Aram M, Whitelegge Julian P, Faull Kym F, Valentine Joan Selverstone   Local unfolding in a destabilized, pathogenic variant of superoxide dismutase 1 observed with H/D exchange and mass spectrometry The Journal of biological chemistry, 2006; 281(26): 18167-76.
Danzeisen Ruth, Achsel Tilmann, Bederke Ulrich, Cozzolino Mauro, Crosio Claudia, Ferri Alberto, Frenzel Malte, Gralla Edith Butler, Huber Lea, Ludolph Albert, Nencini Monica, Rotilio Giuseppe, Valentine Joan Selverstone, Carrì Maria Teresa   Superoxide dismutase 1 modulates expression of transferrin receptor Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 2006; 11(4): 489-98.
Strange Richard W, Antonyuk Svetlana V, Hough Michael A, Doucette Peter A, Valentine Joan Selverstone, Hasnain S Samar   Variable metallation of human superoxide dismutase: atomic resolution crystal structures of Cu-Zn, Zn-Zn and as-isolated wild-type enzymes Journal of molecular biology, 2006; 356(5): 1152-62.
Sanchez Raylene J, Srinivasan Chandra, Munroe William H, Wallace Matthew Alan, Martins Jacob, Kao Tina Y, Le Kate, Gralla Edith Butler, Valentine Joan Selverstone   Exogenous manganous ion at millimolar levels rescues all known dioxygen-sensitive phenotypes of yeast lacking CuZnSOD Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 2005; 10(8): 913-23.
Banci Lucia, Bertini Ivano, D'Amelio Nicola, Gaggelli Elena, Libralesso Elisa, Matecko Irena, Turano Paola, Valentine Joan Selverstone   Fully metallated S134N Cu,Zn-superoxide dismutase displays abnormal mobility and intermolecular contacts in solution The Journal of biological chemistry, 2005; 280(43): 35815-21.
Wallace Matthew Alan, Bailey Sasaneh, Fukuto Jon M, Valentine Joan Selverstone, Gralla Edith Butler   Induction of phenotypes resembling CuZn-superoxide dismutase deletion in wild-type yeast cells: an in vivo assay for the role of superoxide in the toxicity of redox-cycling compounds Chemical research in toxicology, 2005; 18(8): 1279-86.
Rodriguez Jorge A, Shaw Bryan Francis, Durazo Armando, Sohn Se Hui, Doucette Peter A, Nersissian Aram M, Faull Kym F, Eggers Daryl K, Tiwari Ashutosh, Hayward Lawrence J, Valentine Joan Selverstone   Destabilization of apoprotein is insufficient to explain Cu,Zn-superoxide dismutase-linked ALS pathogenesis Proceedings of the National Academy of Sciences of the United States of America, 2005; 102(30): 10516-21.
Valentine Joan Selverstone, Doucette Peter A, Zittin Potter Soshanna   Copper-zinc superoxide dismutase and amyotrophic lateral sclerosis Annual review of biochemistry, 2005; 74(5): 563-93.
Doucette Peter A, Whitson Lisa J, Cao Xiaohang, Schirf Virgil, Demeler Borries, Valentine Joan Selverstone, Hansen Jeffrey C, Hart P John   Dissociation of human copper-zinc superoxide dismutase dimers using chaotrope and reductant. Insights into the molecular basis for dimer stability The Journal of biological chemistry, 2004; 279(52): 54558-66.
Pelling Andrew E, Sehati Sadaf, Gralla Edith B, Valentine Joan S, Gimzewski James K   Local nanomechanical motion of the cell wall of Saccharomyces cerevisiae Science (New York, N.Y.), 2004; 305(5687): 1147-50.
Jensen Laran T, Sanchez Raylene J, Srinivasan Chandra, Valentine Joan Selverstone, Culotta Valeria Cizewski   Mutations in Saccharomyces cerevisiae iron-sulfur cluster assembly genes and oxidative stress relevant to Cu,Zn superoxide dismutase The Journal of biological chemistry, 2004; 279(29): 29938-43.
Wallace Matthew Alan, Liou Lee-Loung, Martins Jacob, Clement Matthew H S, Bailey Sasaneh, Longo Valter D, Valentine Joan Selverstone, Gralla Edith Butler   Superoxide inhibits 4Fe-4S cluster enzymes involved in amino acid biosynthesis. Cross-compartment protection by CuZn-superoxide dismutase The Journal of biological chemistry, 2004; 279(31): 32055-62.
Hough Michael A, Grossmann J Günter, Antonyuk Svetlana V, Strange Richard W, Doucette Peter A, Rodriguez Jorge A, Whitson Lisa J, Hart P John, Hayward Lawrence J, Valentine Joan Selverstone, Hasnain S Samar   Dimer destabilization in superoxide dismutase may result in disease-causing properties: structures of motor neuron disease mutants Proceedings of the National Academy of Sciences of the United States of America, 2004; 101(16): 5976-81.
Carroll Mark C, Girouard Jody B, Ulloa Janella L, Subramaniam Jamuna R, Wong Phillip C, Valentine Joan Selverstone, Culotta Valeria Cizewski   Mechanisms for activating Cu- and Zn-containing superoxide dismutase in the absence of the CCS Cu chaperone Proceedings of the National Academy of Sciences of the United States of America, 2004; 101(16): 5964-9.
Elam Jennifer Stine, Malek Kevin, Rodriguez Jorge A, Doucette Peter A, Taylor Alexander B, Hayward Lawrence J, Cabelli Diane E, Valentine Joan Selverstone, Hart P John   An alternative mechanism of bicarbonate-mediated peroxidation by copper-zinc superoxide dismutase: rates enhanced via proposed enzyme-associated peroxycarbonate intermediate The Journal of biological chemistry, 2003; 278(23): 21032-9.
Strange Richard W, Antonyuk Svetlana, Hough Michael A, Doucette Peter A, Rodriguez Jorge A, Hart P John, Hayward Lawrence J, Valentine Joan S, Hasnain S Samar   The structure of holo and metal-deficient wild-type human Cu, Zn superoxide dismutase and its relevance to familial amyotrophic lateral sclerosis Journal of molecular biology, 2003; 328(4): 877-91.
Valentine Joan Selverstone, Hart P John   Misfolded CuZnSOD and amyotrophic lateral sclerosis Proceedings of the National Academy of Sciences of the United States of America, 2003; 100(7): 3617-22.
Potter Soshanna Zittin, Valentine Joan Selverstone   The perplexing role of copper-zinc superoxide dismutase in amyotrophic lateral sclerosis (Lou Gehrig's disease) Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 2003; 8(4): 373-80.
Shipp Eric L, Cantini Francesca, Bertini Ivano, Valentine Joan Selverstone, Banci Lucia   Dynamic properties of the G93A mutant of copper-zinc superoxide dismutase as detected by NMR spectroscopy: implications for the pathology of familial amyotrophic lateral sclerosis Biochemistry, 2003; 42(7): 1890-9.
Fabrizio Paola, Liou Lee-Loung, Moy Vanessa N, Diaspro Alberto, Valentine Joan Selverstone, Gralla Edith Butler, Longo Valter D   SOD2 functions downstream of Sch9 to extend longevity in yeast Genetics, 2003; 163(1): 35-46.
Valentine Joan Selverstone   Do oxidatively modified proteins cause ALS? Free radical biology & medicine, 2002; 33(10): 1314-20.
Hayward Lawrence J, Rodriguez Jorge A, Kim Ji W, Tiwari Ashutosh, Goto Joy J, Cabelli Diane E, Valentine Joan Selverstone, Brown Robert H   Decreased metallation and activity in subsets of mutant superoxide dismutases associated with familial amyotrophic lateral sclerosis The Journal of biological chemistry, 2002; 277(18): 15923-31.
Rodriguez Jorge A, Valentine Joan S, Eggers Daryl K, Roe James A, Tiwari Ashutosh, Brown Robert H, Hayward Lawrence J   Familial amyotrophic lateral sclerosis-associated mutations decrease the thermal stability of distinctly metallated species of human copper/zinc superoxide dismutase The Journal of biological chemistry, 2002; 277(18): 15932-7.
Roe James A, Wiedau-Pazos Martina, Moy Vanessa N, Goto Joy J, Gralla Edith Butler, Valentine Joan Selverstone   In vivo peroxidative activity of FALS-mutant human CuZnSODs expressed in yeast Free radical biology & medicine, 2002; 32(2): 169-74.
Sisemore Marlene F., Selke Matthias, Burstyn Judith N., Valentine Joan Selverstone   Metalloporphyrin Peroxo Complexes of Iron(III), Manganese(III), and Titanium(IV). Comparative Studies Demonstrating That the Iron(III) Complex Is Extremely Nucleophilic Inorganic chemistry, 1997; 36(6): 979-984.
Nam Wonwoo, Baek Seung Joong, Lee Kyoung Ah, Ahn Byung Tae, Muller James G., Burrows Cynthia J., Valentine Joan Selverstone   Nickel Complexes as Antioxidants. Inhibition of Aldehyde Autoxidation by Nickel(II) Tetraazamacrocycles Inorganic chemistry, 1996; 35(23): 6632-6633.
Lu Yi, Roe James A., Bender Christopher J., Peisach Jack, Banci Lucia, Bertini Ivano, Gralla Edith B., Valentine Joan Selverstone   New Type 2 Copper-Cysteinate Proteins. Copper Site Histidine-to-Cysteine Mutants of Yeast Copper-Zinc Superoxide Dismutase Inorganic chemistry, 1996; 35(6): 1692-1700.
Nam Wonwoo, Kim Hyo Jin, Kim Seong Hoon, Ho Raymond Y. N., Valentine Joan Selverstone   Metal Complex-Catalyzed Epoxidation of Olefins by Dioxygen with Co-Oxidation of Aldehydes. A Mechanistic Study Inorganic chemistry, 1996; 35(4): 1045-1049.

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